B P International

Chlorpyrifos pesticides are endocrine disruptors, inhibitors of acetyl cholinesterase, used to control pests and prime contributors to indoor pollution in retail stores. Seven selected locally sourced adsorbents; Bone charcoal (BCA), corncobs, cotton seed, kokoli, sawdust, coconut shell (CSA) and Muruchi were evaluated. Only BCA and CSA shows peaks and were further examined at adsorptive temperatures of 283, 293, 303 and 313K. Adsorbents physical properties that is, micro pore surface area, total pore volume; micro pore volume, particle density and true density were measured and compared. Results from gas chromatography and surface characterization revealed that the adsorptive capacities of carbon (CSA) at various temperatures were higher than that of carbon (BCA). The plots of Langmuir and Freundlich Isotherms were well fitted by the measured adsorption data. The parameters of adsorption equation for both Langmuir and Freundlich were determined for the two adsorbents, which indicat...

A micro porous activated carbon (JAC) was synthesis from Jatropha curcas shell an agricultural waste by chemical activation using KOH. The JAC was modified with triethanolamine (TEA) to produce (JAC-TEA). The performance of both adsorbents in CO 2 capture study was evaluated in a cylindrical glass column equipped with a digital mass balance. The effect of adsorbent dosage (0.5-1.5 g) and temperature (30-60°C) as a function of time was investigated. The results showed that CO 2 adsorption capacities of the adsorbents increase on amine loading and adsorbent dosage (bed height), while the adsorption capacity decreases with increase in temperature. Adsorption capacity of JAC and JAC-TEA were 66 and 78 mg/g respectively. Crystallinity, morphological structure and surface functional groups of adsorbents were characterized using X-ray diffraction, Scanning electron microscopy and Fourier Transformed  Infra red spectrophotometer respectively, while the surface areas and porosity were d...