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An Effect of Precursor Concentration on ZnO Thin Films Prepared by Dip Coating Method | Chapter 08 | New Insights on Chemical Research Vol. 1

Zinc Oxide (ZnO) thin films have been successfully coated onto glass substrates at various solutions concentration (0.1 M, 0.2 M and 0.3 M) by Low cost SILAR coating technique. The film thickness was estimated using weight gain method and it revealed that the film thickness increased with solution concentration values. The prepared film structural, morphological and optical properties were studied using X-ray diffraction (XRD), scanning electron microscope (SEM) and UV-Vis-NIR spectrophotometer respectively. The structure of the films were found to be hexagonal structure with polycrystalline in nature with preferential orientation along (002) plane. X-ray line profile analysis was used to evaluate the micro structural parameters such as crystallite size, micro strain, dislocation density and stacking fault probability. The value of the crystalline size is increased by increasing the concentration of the solution. The average crystalline size was estimated at in the range of 26 nm to...

Optical Properties of Te-Based Chalcogenide Alloys in the Mid- and Far Infrared Regions | Chapter 05 | New Advances in Materials Science and Engineering Vol. 1

Ternary telluride alloys of Ge–Se(Sb)–Te and Si–Ge(Ga)–Te systems are synthesized in glassy and crystalline states for use in the terahertz frequency range. The transmission spectra of the obtained alloys are measured and studied in a wide wavelength range from 0.75 to 300 μm. The possible mechanisms of their formation are discussed. A comparative analysis of the results shows that the Ge 14 Sb 28 Te 56 alloy of the GST system is most promising. Its phonon spectrum is in the range of 40– 280 cm –1 , limiting the long-wavelength transmission window of this alloy by 35 μm. Optimization of the Ge 14 Sb 28 Te 56 composition, the removal of impurities, and heat treatment will promote a further decrease in the absorbance in the far-infrared spectrum of this alloy. Author(s) Details V. A. Ryzhov Ioffe Institute, St. Petersburg, 194021, Russia. Read full article: http://bp.bookpi.org/index.php/bpi/catalog/view/66/782/605-1 View Volume: https://doi.org/10.9734/bpi/namse/...

Effect of Concentration on Morphological, Optical and Electrical Properties of Copper Doped Zinc Oxide Thin Films Deposited by Electrostatic Spray Pyrolysis (ESP) Technique | Chapter 03 | New Advances in Materials Science and Engineering Vol. 1

Pure zinc oxide (ZnO) and copper (Cu) doped ZnO thin films were synthesised from the precursor’s concentrations (zinc acetate and copper acetate) onto glass substrate via electrostatic spray pyrolysis (ESP) deposition technique at 350°C in air ambient with different Cu doping concentrations (0%, 5%, 10%, 15% and 20%). The thin films were analysed with regards to its morphological, optical, and electrical properties before and after annealing. The results indicate that the annealing of the thin films leads to improved surface morphology and better crystallinity quality. Nanofibers were observed around the nucleation centre in the pure ZnO thin films. The absorbance was recorded in the wavelength range of 230 nm to 1100 nm, and the optical transmission of the films was found to increase for increasing doping concentration of Cu up to 370 nm and then decreased for higher wavelengths. ZnO:Cu films displayed high optical transparency which is around 86% - 98% in the visible and infrared ...