Optical Properties of Te-Based Chalcogenide Alloys in the Mid- and Far Infrared Regions | Chapter 05 | New Advances in Materials Science and Engineering Vol. 1
Ternary telluride alloys of
Ge–Se(Sb)–Te and Si–Ge(Ga)–Te systems are synthesized in glassy and crystalline
states for use in the terahertz frequency range. The transmission spectra of
the obtained alloys are measured and studied in a wide wavelength range from
0.75 to 300 μm. The possible mechanisms of their formation are discussed. A comparative
analysis of the results shows that the Ge14Sb28Te56
alloy of the GST system is most promising. Its phonon spectrum is in the range
of 40– 280 cm–1, limiting the long-wavelength transmission window of
this alloy by 35 μm. Optimization of the Ge14Sb28Te56
composition, the removal of impurities, and heat treatment will promote a
further decrease in the absorbance in the far-infrared spectrum of this alloy.
Author(s) Details
V. A. Ryzhov
Ioffe Institute, St.
Petersburg, 194021, Russia.
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