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Biodiesel Synthesis from Cameroon Palm Kernel Seed Oil | Chapter 1 | Current Strategies in Biotechnology and Bioresource Technology Vol. 1

Aims: This study was aimed at synthesizing and characterizing a biodiesel from Cameroon palm kernel oilseed. Study Design: Synthesis was carried out on purified kernel oil by trans-esterification using methanol in basic medium. Place and Duration of Study: Laboratory work was effectively carried out in the Department of Chemical Engineering (Ahmadu Bello University, Nigeria) and at the Kaduna Refinery and Petrochemical Company (K.R.P.C), Nigeria, in the early part of the year 2017. Methodology: Oil was extracted from Cameroon palm kernel seeds, which constitutes an agricultural industrial waste, by mechanical expression, was purified and analysed. Palm kernel oil (PKO) biodiesel was synthesised by trans-esterification in methanol with potassium hydroxide (KOH) as a base catalyst at the mass ratio PKO to methanol to KOH of 100:20:1. Results: The yield of optimised synthesis of biodiesel was 97%, with a useful by-product (glycerol) which has potential pharmaceutical, cosmetic and engi...

Biodiesel Process Intensification | Chapter 03 | New Insights on Chemical Research Vol. 1

An investigation on process intensification on biodiesel production was carried with Jatropha curcas seed oil, methanol and five solid base catalysts in a process intensified pilot plant. This Process Intensify Pilot Plant had not the following unit operations as in conventional plants; Neutralizer, Washer, Dryer, Heat exchanger and Condenser to reduce production cost. Five samples of biodiesel were produced with 3 moles of methanol to 1 mole of oil and 1.5 % catalyst loading (w/w of oil). Methyl ester yields of 97.4, 96.94, 95.76, 99.99 and 98.25 % catalyzed by bulk calcium oxide (CaO), super base calcium oxide (CaO/(NH4)2CO3), bulk magnesium oxide (MgO), calcium oxide/magnesium oxide (CaO/MgO) and 10 % impregnated potassium on calcium oxide/magnesium oxide (K-CaO/MgO) were obtained respectively. The products were analyzed in accordance with ASTM, EN and ISO standards for biodiesel and were found satisfactory for use in compression ignition engines. All the biodiesel samples were f...

Physicochemical Properties of Rubber (Hevea brasiliensis) Seed Oil, Its Biodiesel and Blends with Diesel | Chapter 02 | Advances in Applied Science and Technology Vol. 5

Literature search shows that research on feed stocks for the production of biodiesel in Africa have not been well documented. To close this gap, a research project was initiated to measure the fuel and physicochemical properties of common vegetable oils in Nigeria. The works on cashew nut oil has been reported and that of rubber seed oil is being reported in this paper. Rubber tree seed oil has several   industrial   applications   but   not   all   the   fuel   and   physicochemical   properties   are   available   in literature, hence   the   aim   of   this   study   is   to   provide   the   properties   of   not   only   the   oil   but   also   the biodiesel, 20% and 10% blends with diesel. For the purpose of characterization, the oil was extracted by soxhlet extraction and the free fatty acids was measured and found to be 23...