Stochastically-Induced Quantum-to-Classical Transition: The Lindemann Relation, Maximum Density at the He Lambda Point and Water-Ice Transition | Chapter 5 | Advances and Trends in Physical Science Research Vol. 2
In the present paper,
by using the quantum stochastic hydrodynamic analogy (SQHA), the transition
between gas, liquid and solid phases, made of structureless particles, have
been analyzed. The interest for the quantum hydrodynamic analogy (QHA) has been
recently growing by its strict relation with the Schrödinger mechanics. The
SQHA shows that the quantum behaviour is maintained on a distance shorter than
the theory-defined quantum correlation length (c). When the physical length of
the problem is larger than c, the model shows that the quantum (potential)
interactions may have a finite range of interaction maintaining the non-local
behaviour on a finite distance “quantum non-locality length” q (with q >c
). The present work shows the realization of “classical” phases (gas and van
der Waals liquids), when the mean molecular distance is larger than the quantum
non-locality length q. On the other hand, when the mean molecular distance
becomes smaller than q or than c phases transitions such as to solid crystal
or to superfluid appear, respectively. The model shows that the quantum
character of the matter emerges as a consequence of the random noise
suppression generated by the quantum potential below the induced noise
correlation length. The model explains
the Lindemann empirical law about the mean square deviation of atoms from the
equilibrium position at melting point of crystal, and shows a connection
between the maximum density at the He lambda point and that one at the
water-ice solidification point. The SQHA shows that both the linearity of the
particle interaction and the reduction of amplitude of stochastic fluctuations
elicited the emergence of quantum behavior. The SQHA model also shows that the
nonlinear behavior of physical forces, other than to play an important role in
the establishing of thermodynamic equilibrium, is a necessary condition to pass
from the quantum to the classical phases and that fluctuation alone are not
sufficient.
Biography of author(s)
Piero Chiarelli
National Council of
Research of Italy, Area of Pisa, 56124 Pisa, Moruzzi 1, and Interdepartmental
Center “E. Piaggio” University of Pisa, Italy.
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View Volume: https://doi.org/10.9734/bpi/atpsr/v2
View Volume: https://doi.org/10.9734/bpi/atpsr/v2
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